Product ID:BASE NEUTRAL CALIBRATION CHECKCOMPOUND MIX(
MSDS Date:02/07/1992
FSC:6850
NIIN:00N034467
MSDS Number: BQBQY

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

(ORAL,RAT) 2000 MG/KG

CAS: 206-44-0

RTECS: LL4025000

Fraction By Weight: 0.2%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ACENAPHTHENE (SARA III)

CAS: 83-32-9

RTECS: AB1000000

Fraction By Weight: 0.2%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BENZENE, P-DICHLORO; (1,4-DICHLOROBENZENE) (SARA III).

CAS: 106-46-7

RTECS: CZ4550000

Fraction By Weight: 0.2%

OSHA PEL 75 PPM

ACGIH TLV: 10 PPM,A3 9394

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

1,3-BUTADIENE, HEXACHLORO-; (HEXACHLORO-1,3-BUTADIENE);

CAS: 87-68-3

RTECS: EJ0700000

Fraction By Weight: 0.2%

OSHA PEL 0.02 PPM

ACGIH TLV: 0.02 PPM, S

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

DIPHENYLAMINE,N-NITROSE-;(N-NITROSODIPHENYLAMINE) (SARA

CAS: 86-30-6

RTECS: JJ9800000

Fraction By Weight: 0.2%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

PHTHALIC ACID, DIOCYTYL ESTER; (N-DIOCTYLPHTHALATE) (SARA

CAS: 117-84-0

RTECS: TI1925000

Fraction By Weight: 0.2%

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

(ORAL,RAT) 50 MG/KG

CAS: 50-32-8

RTECS: DJ3675000

Fraction By Weight: 0.2%

OSHA PEL 0.2 MG/M3

ACGIH TLV: A2, MG/M3;9394

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

(ORAL,RAT)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 98.6%

OSHA PEL 500 PPM, C

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CHLOROCARBON MATLS HAVE PRODUCED SENSIT OF THE

RTECS: 9999999ZZ

A SIMILAR EFT IN HUMANS. ADRENOMIMETICS (E.G.,

RTECS: 9999999ZZ

SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY

RTECS: 9999999ZZ

GROUP 2B (IARC),

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:MAY BE FATAL IF INHALED. HARMFUL IF
SWALLOWED. CONTAINS MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER. LACRIMATION. IRRIT SKIN. DERMATITIS. HDCH. DIZZINESS.
NARCOSIS. LIVER & KIDNEY DAM AGE. SEVERAL CHRONIC INHAL STUDIES
REPORTED BY NIOSH REVEALED THAT 10,000 PPM SHOWED SLIGHT LIVER &
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:DICHLOROBENZENE (1,4):GRP 2B(IARC);
ANTIC TO BE A CARCIN(NTP).BENZO (A) PYRENE:GRP 2A(IARC),ANTIC TO BE
A CARCIN(ING 12)
Effects of Overexposure:HLTH HAZ: KIDNEY CHANGES. METHYLENE CHLORIDE
HAS BEEN SHOWN TO INCREASE THE RATE OF SPONTANEOUSLY OCCURING
MALIGNANT TUMORS IN ONE STRAIN OF LAB MIC & BENIGN TUMORS IN LAB
STUDIES, HAVE INDICATED A NE GATIVE RESPONSE. METHYLENE CHLORIDE IS
NOT BELIEVED TO POSE A CARCIN RISK TO MAN WHEN HANDLED AS
RECOMMENDED.(SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE: FLUSH WITH WATER FOR AT LEAST 15 MIN. SKIN: PROMPTLY
WASH SKIN WITH MILD SOAP AND LARGE VOLUMES OF WATER. REMOVE
CONTAMINATED CLOTHING. INHAL: IMMED MOVE TO FRESH AIR. GIVE OXYGEN
IF BREATHING IS LABORED. IF BREATHING STOPS, GIVE ARTIFICIAL
RESPIRATION. INGEST:CALL MD IMMEDIATELY .

Extinguishing Media:WATER, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THE FOLLOWING TOXIC VAPORS ARE FORMED
WHEN THIS MATERIAL IS HEATED TO DECOMP: HYDROGEN CHLORIDE, PHOSGENE

Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
AREA. METHYLENE CHLORIDE VAPORS ARE HEAVIER THAN AIR AND WILL
COLLECT IN LOW AREAS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINER.
Other Precautions:POSSIBLE CANCER HAZARD. NO SMOKING IN AREA OF USE. DO
NOT USE IN THE GENERAL VICINITY OF ARC WELDING, OPEN FLAMES, OR HOT
SURFACES. HEAT AND/OR UV RADIATION MAY CAUSE THE FORMATION OF HCL
AND/OR PHOSG ENE .

Respiratory Protection:WEAR FACE MASK WITH ORGANIC VAPOR CANISTER. WEAR
NIOSH/MSHA APPROVED RESPIRATORY PROTECTION.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES
Supplemental Safety and Health
MFR TRADE NAME/PART NO: 1ML, 48464. EFTS OF OVEREXP:CH*2CL*2 IS
METABOLIZED TO CO & CAN STRESS CARDIOVASCULAR SYS DUE TO INCR
CARBOXYHEMOGLOBIN. IN RATS METHYLENE CHLORIDE HAS BEEN SHOWN TO
PRODUCE SI GNIF INCR IN SALIVARY GLAND TUMORS. (ING 9)

HCC:T4
Boiling Pt:B.P. Text:104F,40C
Melt/Freeze Pt:M.P/F.P Text:-143F,-97C
Vapor Pres:349
Vapor Density:2.93
Spec Gravity:1.320
Evaporation Rate & Reference:0.71 (ETHER=1)
Solubility in Water:1.6
Appearance and Odor:CLEAR COLORLESS LIQUID, ETHER LIKE ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG BASES, OXIDIZING AGENTS.
Stability Condition to Avoid:LIQUID OXYGEN OR OTHER STRONG OXIDANTS MAY
FORM EXPLOSIVE MIXTURES WITH METHYLENE CHLORIDE.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE.

Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE AND
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.